PostgreSQL 9.4beta1 was released last week and windows binaries for both 32-bit and 64-bit are already available to try it out from http://www.postgresql.org/download/windows. Since this is a beta release, there are no installers yet, just the zip binary archive.
To make the pot a little sweeter, we've setup the PostGIS windows build bot (Winnie) to automatically build for 9.4 - PostGIS 2.2.0 development branch and pgRouting 2 branches whenever there is a change in the code. We also have the pointcloud extension in the extras folder. If you are on 9.3, we've got 2.2 binaries for that as well. The PostGIS/pgRouting related stuff you can find at http://postgis.net/windows_downloads in the 9.4 folder.
For the rest of this article we'll discuss a couple of stumbling blocks you may run into.
Much of what we'll describe here is windows specific, but thanks to the beauty of extensions and GUCs, the extension install and GUC setting part for PostGIS is applicable to all operating systems.